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Crystallization

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A Review of Experimental Methods for Nucleation Rate Determination in Large-Volume Batch and Microfluidic Crystallization. Lovinger AJ, Davis DD, Lotz B (1991) Temperature-dependence of structure and morphology of syndiotactic polypropylene and epitaxial relationships with isotactic polypropylene. Macromolecules 24(2):552–560. https://doi.org/10.1021/ma00002a033 Zhang YF, Li D, Chen QJ (2017) Preparation and nucleation effects of nucleating agent hexahydrophthalic acid metal salts for isotactic polypropylene. Colloid Polym Sci 295(10):1973–1982. https://doi.org/10.1007/s00396-017-4176-8 Hoffman JD (1982) Role of reptation in the rate of crystallization of polyethylene fractions from the melt. Polymer 23(5):656–670. https://doi.org/10.1016/0032-3861(82)90048-9

Burns JR, Turnbull D (1966) Kinetics of crystal nucleation in molten isotactic polypropylene. J Appl Phys 37(11):4021–4026. https://doi.org/10.1063/1.1707969 The Essential Guide to Crystals: All the Crystals You Will Ever Need for Health, Healing, and Happiness (Essential Guides) Fillon B, Wittmann JC, Lotz B et al (1993) Self-nucleation and recrystallization of isotactic polypropylene (alpha-phase) investigated by differential scanning calorimetry. J Polym Sci Part B Polym Phys 31(10):1383–1393. https://doi.org/10.1002/polb.1993.090311013 Lotz B (2014) A new epsilon crystal modification found in stereodefective lsotactic polypropylene samples. Macromolecules 47(21):7612–7624. https://doi.org/10.1021/ma5009868 Lotz B, Lovinger AJ, Cais RE (1988) Crystal-structure and morphology of syndiotactic polypropylene single-crystals. Macromolecules 21(8):2375–2382. https://doi.org/10.1021/ma00186a013

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Koutsky JA, Walton AG, Baer E (1967) Nucleation of polymer droplets. J Appl Phys 38(4):1832–1839. https://doi.org/10.1063/1.1709769 Since the first publication of this definitive work nearly 40 years ago, this fourth edition has been completely rewritten. Crystallization is used at some stage in nearly all process industries as a method of production, purification or recovery of solid materials.

Power Crystals: The Ultimate Guide to Magical Crystals, Gems, and Stones for Healing and Transformation As crystallization is concerned with the phase change in solid–liquid systems, analysis of crystallization processes starts with consideration of phase diagrams. In this chapter we will show how phase diagrams help to select a crystallization method, and to determine the yield and the temperature of a crystallization process. The industrially relevant features of the main crystallization methods are also presented. Kaminsky W (1998) Highly active metallocene catalysts for olefin polymerization. J Chem Soc, Dalton Trans 9:1413–1418. https://doi.org/10.1039/A800056E Incorporating all the recent developments and applications of crystallization technology, Crystallization gives clear accounts of the underlying principles, a review of the past and current research themes and guidelines for equipment and process design. This new edition introduces and enlarges upon such subjects as: Step 5: After some time there will be a point at which no more sugar can be dissolved in water. This stage is the saturation point, and the solution is referred to as a saturated solution

Crystallization Examples

Lezak E, Bartczak Z, Galeski A (2006) Plastic deformation behavior of beta-phase isotactic polypropylene in plane-strain compression at room temperature. Polymer 47(26):8562–8574. https://doi.org/10.1016/j.polymer.2006.10.016 Tranchida D, Mileva D, Resconi L et al (2015) Molecular and thermal characterization of a nearly perfect isotactic poly(propylene). Macromol Chem Phys 216(22):2171–2178. https://doi.org/10.1002/macp.201500189

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